2-Propylzinc broMide solution 0.5 M in THF
2-Propylzinc bromide
CAS: 77047-87-1
Molecular Formula: C3H7BrZn
2-Propylzinc broMide solution 0.5 M in THF - Names and Identifiers
2-Propylzinc broMide solution 0.5 M in THF - Physico-chemical Properties
| Molecular Formula | C3H7BrZn |
| Molar Mass | 188.37 |
| Density | 0.963g/mLat 25°C |
| Flash Point | -20°C |
| Water Solubility | Reacts with water. |
| Exposure Limit | ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)OSHA: TWA 200 ppm(590 mg/m3)NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
| Storage Condition | 2-8°C |
| Sensitive | Air Sensitive |
2-Propylzinc broMide solution 0.5 M in THF - Risk and Safety
| Risk Codes | R11 - Highly Flammable R19 - May form explosive peroxides R36/37/38 - Irritating to eyes, respiratory system and skin. R40 - Limited evidence of a carcinogenic effect R14/15 - |
| Safety Description | S7 - Keep container tightly closed. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) S36/37 - Wear suitable protective clothing and gloves. S16 - Keep away from sources of ignition. |
| UN IDs | UN 3399 4.3/PG 2 |
| WGK Germany | 3 |
| HS Code | 29319090 |
| Hazard Class | 4.3 |
2-Propylzinc broMide solution 0.5 M in THF - Introduction
2-Propylzinc bromide is an organic compound with the chemical formula C3H7ZnBr. The following is a description of its nature, use, preparation and safety information:
Nature:
-Appearance: 2-Propylzine bromide is a colorless to yellow liquid.
-Solubility: It is soluble in non-polar solvents, such as ether, dimethylformamide and disulfide.
-Stability: It is easily decomposed by moisture in the air, and may cause spontaneous combustion.
Use:
-2-Propylzine bromide can be used as an important reagent in organic synthesis, commonly used for the alkylation of halogenated raw materials.
-It can be used to prepare other organic zinc reagents, such as 2-butyl zinc compounds.
Preparation Method:
2-Propylzinc bromide can be prepared by reacting propylmagnesium bromide with zinc chloride. The specific steps are as follows:
1. Under anhydrous conditions, the propyl magnesium bromide is stirred with zinc chloride dissolved in disulfide.
2. The reaction mixture was filtered to give the 2-Propylzinc bromide product.
Safety Information:
- 2-Propylzinc bromide is irritating and corrosive and may cause damage to the eyes, skin and respiratory system when in contact.
-Wear protective equipment, including chemical protective gloves, goggles, and respiratory protection.
-When in contact with moisture in the air, toxic gases may be produced.
-Do not contact with strong oxidants and strong acids.
-Store away from fire and heat sources and in a cool, dry and well-ventilated place.
Please note that the handling of such chemicals should be carried out in a suitable laboratory environment and follow relevant safe operating procedures.
Nature:
-Appearance: 2-Propylzine bromide is a colorless to yellow liquid.
-Solubility: It is soluble in non-polar solvents, such as ether, dimethylformamide and disulfide.
-Stability: It is easily decomposed by moisture in the air, and may cause spontaneous combustion.
Use:
-2-Propylzine bromide can be used as an important reagent in organic synthesis, commonly used for the alkylation of halogenated raw materials.
-It can be used to prepare other organic zinc reagents, such as 2-butyl zinc compounds.
Preparation Method:
2-Propylzinc bromide can be prepared by reacting propylmagnesium bromide with zinc chloride. The specific steps are as follows:
1. Under anhydrous conditions, the propyl magnesium bromide is stirred with zinc chloride dissolved in disulfide.
2. The reaction mixture was filtered to give the 2-Propylzinc bromide product.
Safety Information:
- 2-Propylzinc bromide is irritating and corrosive and may cause damage to the eyes, skin and respiratory system when in contact.
-Wear protective equipment, including chemical protective gloves, goggles, and respiratory protection.
-When in contact with moisture in the air, toxic gases may be produced.
-Do not contact with strong oxidants and strong acids.
-Store away from fire and heat sources and in a cool, dry and well-ventilated place.
Please note that the handling of such chemicals should be carried out in a suitable laboratory environment and follow relevant safe operating procedures.
Last Update：2024-04-10 22:29:15
Supplier List
Spot supply
Product Name: Isopropylzinc broMide Visit Supplier Webpage Request for quotationCAS: 77047-87-1
Tel: +86 0571-86722205
Email: sales@chinaskyrun.com
Mobile: +8618958170122
QQ: 2531159185
Wechat: chinaskyrun
Spot supply
Product Name: 2-propylzinc bromide Visit Supplier Webpage Request for quotationCAS: 77047-87-1
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328
WhatsApp: +86-18821248368
Spot supply
Product Name: Isopropylzinc broMide Visit Supplier Webpage Request for quotationCAS: 77047-87-1
Tel: +86 0571-86722205
Email: sales@chinaskyrun.com
Mobile: +8618958170122
QQ: 2531159185
Wechat: chinaskyrun
Spot supply
Product Name: 2-propylzinc bromide Visit Supplier Webpage Request for quotationCAS: 77047-87-1
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328
WhatsApp: +86-18821248368
View History